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Formic Acid 85% is miscible with water and most polar organic solvents, and somewhat soluble in hydrocarbons. In hydrocarbons and in the vapor phase it consists of hydrogen-bonded dimers rather than individual molecules. [1] Owing to its tendency to hydrogen-bond, gaseous formic acid does not obey the ideal gas law. [2] Solid formic acid (two polymorphs) consists of an effectively endless network of hydrogen-bonded formic acid molecules. This relatively complicated compound also forms a low-boiling azeotrope with water (22.4%) and liquid formic acid also tends to supercool.
Formic Acid 85% is miscible with water and most polar organic solvents, and somewhat soluble in hydrocarbons. In hydrocarbons and in the vapor phase it consists of hydrogen-bonded dimers rather than individual molecules. [1] Owing to its tendency to hydrogen-bond, gaseous formic acid does not obey the ideal gas law. [2] Solid formic acid (two polymorphs) consists of an effectively endless network of hydrogen-bonded formic acid molecules. This relatively complicated compound also forms a low-boiling azeotrope with water (22.4%) and liquid formic acid also tends to supercool.
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